Surface reaction dynamics.
نویسندگان
چکیده
The study of surface chemical reaction dynamics is crucial to many important areas of research such as heterogeneous catalysis, photocatalysis, material corrosion and etching, to name just a few. Many fundamental questions, for example mechanisms of important catalytic reactions, rely on the study of surface reaction dynamics. Prof. Gerhard Ertl’s achievements in this area exemplify the importance of this field. During the last few decades, the field of surface reaction dynamics has become one of the most active areas in fundamental physical chemistry research. Surface reaction dynamics studies also have great potential for advancing our understanding of reactions on the surfaces of nanoparticles, which is badly needed. New frontiers have been developed during the past decades. New advanced surface experimental techniques have been developed to probe surface structures and chemical reaction dynamics at a much more detailed level. More detailed dynamics on very different surfaces can be understood from these new experiments. On the other hand, theoretical efforts in surface chemical reaction dynamics have also made significant advances, providing detailed mechanistic understanding of physical and chemical processes at different interfaces. It is quite hopeful that through detailed experimental and theoretical studies, studies of surface dynamics can reach a much higher level. This themed issue includes nine review papers on various topics in surface reaction dynamics; three of the nine papers are tutorial reviews, written by leading experts in the field. In the first a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Rd., Dalian, Liaoning, China 116023 b Institut für Physikalische Chemie, Tammannstrasse 6, 37077, Göttingen, Germany c Dept. Dynamics at Surfaces, Max-Planck-Institut für biophysikalische chemie, Am Fassberg 11, 37077, Göttingen, Germany
منابع مشابه
Reaction Dynamics of NH2+OH on an Interpolated Potential Energy Surface
QCT calculations were performed to study the behavior of energized NH2OH formed by association collision of NH2 radical with OH radical. A potential energy surface that describes the behavior of the title reaction has been constructed by interpolation of ab initio data. H2O, HON, HNO, NH3, O, H2NO, cis or trans-HONH, and H products and two vibrationally energized NH2OH and NH3O adducts were obs...
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ورودعنوان ژورنال:
- Chemical Society reviews
دوره 45 13 شماره
صفحات -
تاریخ انتشار 2016